Emissions Education: Emissions 101

EMIT Technologies believes that education of its’ customers on emissions and compliance solutions is one of its’ primary goals in providing a quality customer experience. Because of this, EMIT has invested in the staff, equipment, and the development of training programs that will provide organizations a better understanding of the emissions hurdles they face and how to address them.

1. What causes emissions to occur?

In order to reduce emissions, modern engines carefully control the amount of fuel they burn. They try to keep the air-to-fuel ratio very close to the “stoichiometric point”, which is the calculated ideal ratio of air to fuel. Theoretically, at this ratio, all of the fuel will be burned using all of the oxygen in the air. The stoichiometric ratio for Natural Gas is approximately 17.2:1, meaning that for each pound of Fuel (Natural Gas) 17.2 pounds of air will be burned. The fuel mixture actually varies from the ideal ratio quite a bit during load changes. Sometimes the mixture can be lean (an air-to-fuel ratio higher than 17.2), and other times the mixture can be rich (an air-to-fuel ratio lower than 17.2)

The emissions from the combustion of natural gas (CH4) consists of at least 17 intermediate chemical species that occur during the conversion to CO2 & H2O. These intermediate species are ideally formed and consumed in the combustion process. However, under non-ideal conditions, not all of the intermediates are consumed fully and thus are emitted in the exhaust of the engine.

The major intermediates that are emitted are: CO, NO, NO2 (collectively considered NOx), and VOC’s (including formaldehyde [HCHO]).

2. What are emissions from a natural gas SI internal combustion engine?

There are a number of chemical elements that are found in the exhaust from a natural gas fired engine. The main emissions are:

  • Nitrogen gas (N2) – Air is 78-percent nitrogen gas, and most of this passes right through the engine.
  • Carbon dioxide (CO2) – The carbon in the fuel bonds with the oxygen in the air.
  • Water vapor (H2O) – The hydrogen in the fuel bonds with the oxygen in the air.

These primary emissions are mostly benign (although carbon dioxide emissions are believed to contribute to global warming). However, because the combustion process is never perfect, some smaller amounts of more harmful emissions are also produced in engines:

  • Carbon monoxide (CO) – A poisonous gas that is colorless and odorless.
  • Hydrocarbons or volatile organic compounds (VOCs) including formaldehyde (HCHO) – Produced mostly from unburned fuel that evaporates. Sunlight breaks these down to form oxidants, which react with oxides of nitrogen to cause ground level ozone (O3), a major component of smog.
  • Nitrogen oxides (NO and NO2, together called NOx) – Contributes to smog and acid rain, and also causes irritation to human mucous membranes.

These are the three main regulated emissions, and also the ones that catalytic converters are designed to reduce.

3. How are emissions measured?

Emissions are typically measured using the following:

  • Grams Per Brake Horsepower Hour (g/bhp-hr) – This means how many grams of a constituent is emitted by an engine of a specific hp rating over a one hour period.
  • Pounds Per Hour (lbs/hr) – This simply converts the same to pounds of emissions.
  • Tons Per Year (ton/yr or tpy) – We typically see this measurement as a limit to the total amount of emissions allowable for an engine or a site.

4. Why should I be concerned?

There are estimated to be well over 20,000 natural gas engines over 100 hp operating in the United States.  Below is a calculation of the emissions from just one of these engines that is uncontrolled over just one year.

100 HP Uncontrolled Engine Produces:

  • 6500 ppm CO = 17 g/bhp-hr * 100 hp = 1700 g/hr / 28 g/oz = 61 oz/hr * 24 hr = 1464 oz/day / 16 oz/lb = 91.5 lb/day * 365 days/yr = 33397 lb/yr / 2000 lb/ton = 16.5 tons/yr
  • 2200 ppm NOx = 10 g/bhp-hr * 100 hp = 1000 g/hr / 28 g/oz = 35.7 oz/hr * 24 hr = 857 oz/day / 16 oz/lb = 53.5 lb/day * 365 days/yr = 19553 lb/yr / 2000 lb/ton = 9.7 tons/yr

CO = 16.5 tons per year
NOx = 9.7 tons per year
HC = 7 tons per year

Total 33.2 tons per year

A typical dump truck has a capacity of approximately 25 tons. This single uncontrolled 100 hp unit can produce the equivalent of 1.3 dump truck loads of emissions per year.

5. What can I do to address my emissions?

EMIT Technologies in specifically focused on assisting companies in addressing their emissions from natural gas engines. EMIT’s emissions mitigation solutions include a full line of Air Fuel Ratio Controllers and Catalyst that will take the emissions from an engine and significantly reduce their impact on the environment.

100 HP Controlled Engine to 0.5 g/bhp-hr:

CO = .489 tons per year
NOx = .489 tons per year
HC = .25 tons per year

Total 1.228 tons per year

6. What are some critical factors in maintaining emissions compliance?

Exhaust Leaks – NSCR (Three Way) Catalytic converters require a constant oxygen content of 0.5% or less at the inlet to maintain efficient reduction across the catalyst. Excess oxygen content will prevent NOx from being reduced efficiently.

Temperature
  • CO reduction starts to take place at 450° F
  • NOx reduction starts to take place at 750° F
  • Maximum temperature is 1250° F – Above this catalyst damage begins
Catalyst Maintenance
  • Blow ash out of the catalyst element every six months
  • Wash the catalyst every 16-18 months

7. What are items that will damage my catalyst?

Aging
loss of catalytic activity due to a loss of active surface area
Fouling
loss of catalytic activity due to deposits of a carbon material
Mask
oil
Sintering
temperatures over 1250°F
Poisons
phosphorus, sulfur,  heavy metals, anti-seize and glycol (anti-freeze), galvanized flex pipe

8. How are emissions regulated?

Emissions are regulated at a number of levels.

  • The first level of regulation is federal and comes from the EPA. The EPA has issued regulations through New Source Performance Standards (NSPS); the National Emission Standards for Hazardous Air Pollutants (NESHAPs); and the National Ambient Air Quality Standards (NAAQS).
  • The next level of regulation is through the individual states.
  • The final level of regulation is typically at a local or regional level.

EMIT has provided links under Emissions Regulations to the federal regulations and to the agencies involved in establishing and monitoring compliance at a state level.